Each course has its own directory. They are all located in /opt/webwork/courses. For the default admin course, it's course directory would be /opt/webwork/courses/admin. The course.conf and simple.conf files would be located there. Don't create them if they don't exist. You don't need them. The point is that if they do exist, then they might have settings that are overriding what is in localOverrides.conf which you don't want.
If you don't have Mojolicious installed, then you can't do anything with WeBWorK. So install that now. Note that Mojo is the base namespace for everything in the Mojolicious stack, and if you have Mojolicious installed, then you have the stack installed also. If you can run webwork, then you can run the wwsh script. If you can't run the wwsh script, then you also can't run webwork in general. So that is a problem.